God saw all that he had made, and it was very good. And there was evening, and there was morning--the sixth day. Genesis 1:31. The previous verse given was Genesis 1:28. Woman had already been made.
21So the LORD God caused a deep sleep to fall upon the man, and he slept; then He took one of his ribs and closed up the flesh at that place. 22The LORD God fashioned into a woman the rib which He had taken from the man, and brought her to the man.