Genesis 3:16 is not a command; it is a statement of certain consequence. Therefore it cannot be the verse to which Paul refers in 1 Corinthians 14:34. If it were a command, then a woman in labour taking pain relief would be sinning. If it were a command, it would have been given to Adam as "You shall rule over your wife". Nowhere else (that I can think of offhand) is a command given second-hand like this.
There is another reason why this cannot be what Paul is referencing: it says, "your husband shall rule over you"... singular, not corporate, within the context of marriage, not culture and certainly not the church.
Paul's entire message is freedom from the Law found in Christ. It is ludicrous to suggest that he would enforce an Old Covenant command upon the church.