Instead of instantly adding them to some cam site ap thingie (yes I am out of touch with technology), why not try emailing, im-ing or whatnot a while first, and see if you even have anything in common (besides an at-the-ready webcam), and THEN moving to (fully clothed) webcam interaction, and then who knows, maybe living happily ever after.
You're 23, relax and enjoy the ride.....the next step is where the real work begins (marriage).
Peace!!